Synthesis of alkylbenzenes by Friedel-Crafts reactions catalysed by K10-montmorillonite

Autor:	Odette Sieskind, Pierre Albrecht
Rok vydání:	1993
Předmět:	Organic Chemistry Regioselectivity Alcohol Biochemistry Catalysis Acid catalysis chemistry.chemical_compound chemistry Drug Discovery Organic chemistry Alkylbenzenes Aliphatic compound Benzene Friedel–Crafts reaction
Zdroj:	Tetrahedron Letters. 34:1197-1200
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(00)77527-7
Popis:	Monoalkylation of benzene with primary, secondary and tertiary alcohols took place in high yields when K10-montmorillonite was used as acidic catalyst. Unexpected formation of 1-phenylalkylbenzenes occured, beside other isomers with primary alcohols. Monoalkylation with cholestanol and cholesterol was regiospecific and located at C-3. Clay-catalysed alkylbenzene formation may also be of geochemical interest.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0b04ee79a53bb02987c79e616f76cad9 https://doi.org/10.1016/s0040-4039(00)77527-7 Zobrazit plný text záznamu