Electrochemical synthesis and structural characterization of the trinuclear copper(I)–copper(II) complex: bis[bis(triphenylphosphine)copper(I)] [bis(thiosalicylate)copper(II)]
| Autor: | Peter Conrad Healy, Dalius S. Sagatys, Raymond C. Bott |
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| Rok vydání: | 1998 |
| Předmět: |
Thiosalicylic acid
Chemistry Inorganic chemistry Metals and Alloys chemistry.chemical_element General Chemistry Electrochemistry Electrosynthesis Copper Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound Polymer chemistry Materials Chemistry Ceramics and Composites Anodic dissolution Triphenylphosphine Acetonitrile Single crystal |
| Zdroj: | Chemical Communications. :2403-2404 |
| ISSN: | 1364-548X 1359-7345 |
| Popis: | A novel, symmetrical trinuclear copper(I)–copper(II) com-plex, bis[bis(triphenylphosphine)copper(I)][bis(thiosalicylate)copper(II)], [{Cu(PPh3)2}2{Cu(C7H4O2S)2}], has been prepared by anodic dissolution of copper into a solution of triphenylphosphine and thiosalicylic acid in acetonitrile and characterized by single crystal X-ray structure determination as its acetonitrile solvate; characterized also is the 1:3 copper(I) complex, [tris(triphenylphosphine)(thiosalicylic acid-S)copper(I)], formed as an intermediate in the electrosynthesis. |
| Databáze: | OpenAIRE |
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