PREPARATION OF Ca[CrNCS(edta)] BY THE USE OF SOLID-PHASE THERMAL REACTION OF [CrNCS(NH3)5][Ca(edta)]·5H2O

Autor: Akira Uehara, Yoshio Uemori, Eishin Kyuno, Ryokichi Tsuchiya
Rok vydání: 1978
Předmět:
Zdroj: Chemistry Letters. 7:1265-1268
ISSN: 1348-0715
0366-7022
DOI: 10.1246/cl.1978.1265
Popis: [CrNCS(NH3)5][Ca(edta)]·5H2O was prepared by the reaction of [CrNCS(NH3)5]Cl2 with Na2[Ca(edta)]·3.5H2O. The thermal reaction of the complex in the solid-phase was investigated both nonisothermally and isothermally. It was found that the complex was finally converted into Ca[CrNCS(edta)] upon heating in the solid-phase, which was purified from water as the hexahydrate.
Databáze: OpenAIRE