PREPARATION OF Ca[CrNCS(edta)] BY THE USE OF SOLID-PHASE THERMAL REACTION OF [CrNCS(NH3)5][Ca(edta)]·5H2O
Autor: | Akira Uehara, Yoshio Uemori, Eishin Kyuno, Ryokichi Tsuchiya |
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Rok vydání: | 1978 |
Předmět: | |
Zdroj: | Chemistry Letters. 7:1265-1268 |
ISSN: | 1348-0715 0366-7022 |
DOI: | 10.1246/cl.1978.1265 |
Popis: | [CrNCS(NH3)5][Ca(edta)]·5H2O was prepared by the reaction of [CrNCS(NH3)5]Cl2 with Na2[Ca(edta)]·3.5H2O. The thermal reaction of the complex in the solid-phase was investigated both nonisothermally and isothermally. It was found that the complex was finally converted into Ca[CrNCS(edta)] upon heating in the solid-phase, which was purified from water as the hexahydrate. |
Databáze: | OpenAIRE |
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