Synthesis and heterogeneous catalytic activity of covalently immobilized hexamine cation as a magnetically-recoverable nanocatalyst

Autor: Bakhshali Maasoumi, Issa Yavari, Sahar Kangari
Rok vydání: 2015
Předmět:
Zdroj: Journal of the Iranian Chemical Society. 12:1771-1779
ISSN: 1735-2428
1735-207X
DOI: 10.1007/s13738-015-0652-6
Popis: Functionalized magnetic core–shell nanoparticles Fe3O4-SiO2-HMTA are prepared by co-precipitation method and characterized by SEM, TEM, FT-IR, XRD, and VSM. The particles are spherical with an average size of approximately 48 nm. The catalytic activity of these nanoparticles was tested in solvent-free synthesis of coumarin derivatives. The catalyst was readily recycled by the use of an external magnetic field and can be reused four times without significant loss of activity or mass.
Databáze: OpenAIRE