Laccase-mediated oxidation of phenolic derivatives
Autor: | Stephanie G. Burton, Cristina Navarra, Bruno Danieli, Candice M. Goodwin, Sergio Riva |
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Rok vydání: | 2010 |
Předmět: | |
Zdroj: | Journal of Molecular Catalysis B: Enzymatic. 65:52-57 |
ISSN: | 1381-1177 |
DOI: | 10.1016/j.molcatb.2009.12.016 |
Popis: | The laccase-catalyzed oxidation of para -alkyl phenols ( p -cresol, 3,4-dimethylphenol, tyrosol, 2′- O -acetyl-tyrosol) in biphasic systems has been investigated. With all the substrates compounds similar to the so-called “Pummerer's ketone” could be isolated in reasonable yields. Accumulation of this kind of products is due to the fact that these compounds, in contrast to other dimers, are “dead-end” products, as they cannot be further oxidized by the enzyme. |
Databáze: | OpenAIRE |
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