Fourier transform microwave spectroscopy of AgCN and AuCN
| Autor: | Takuya Yamamoto, Mitsutoshi Tanimoto, Satoshi Matsumoto, Toshiaki Okabayashi, Aya Nakane, Hirofumi Kubota, Yoshiro Mitani |
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| Rok vydání: | 2018 |
| Předmět: |
010304 chemical physics
Spectrometer Chemistry Organic Chemistry Analytical chemistry 010402 general chemistry 01 natural sciences Spectral line 0104 chemical sciences Analytical Chemistry Inorganic Chemistry Metal symbols.namesake Fourier transform visual_art 0103 physical sciences Quadrupole symbols visual_art.visual_art_medium Rotational spectroscopy Spectroscopy Microwave |
| Zdroj: | Journal of Molecular Structure. 1164:539-545 |
| ISSN: | 0022-2860 |
| DOI: | 10.1016/j.molstruc.2018.03.002 |
| Popis: | The rotational spectra of AgCN and AuCN were measured using a Fourier-transform microwave (FTMW) spectrometer. AgCN and AuCN were generated in supersonic jets using the pulse-discharge reaction of laser-ablated metal atoms with HCN diluted with Ar. The rotational transitions for 107AgCN, 109AgCN, and AuCN were measured. The quadrupole parameters of the Au and N nuclei were compared with those of other metal monocyanides. |
| Databáze: | OpenAIRE |
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