Acyclic polymeric Reissert compounds: chemically reactive polyamides. 3

Autor:	Harry W. Gibson, Jean Pierre Leblanc
Rok vydání:	1993
Předmět:	Condensation polymer Polymers and Plastics Nitrile Intrinsic viscosity Organic Chemistry Chemical modification Adipoyl chloride Alkylation Inorganic Chemistry chemistry.chemical_compound chemistry Acyl chloride Polymer chemistry Materials Chemistry Moiety Organic chemistry
Zdroj:	Macromolecules. 26:4953-4955
ISSN:	1520-5835 0024-9297
DOI:	10.1021/ma00070a032
Popis:	Open-chain polymeric Reisert compounds, i.e., poly[α-(acylamino)nitrile]s, can be prepared by condensation of bi(α-aminonitrile)s with adipoyl chloride. When the bis(α-aminonitrile) possesses hindered internal secondary amine groups, no high molecular weight polymers could be obtained. From less hindered bis(α-aminonitrile)s amorphous polymeric Reissert compounds of intrinsic viscosity 0.15-0.24 dL.g -1 were synthesized. Their stability was found to exceed in most cases 350°C in nitrogen (5% weight loss). By virtue of the Reissert moiety's acidic proton, chemical modification of such polymers, e.g. by alkylation, provides a means of bulk and surface property control
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0a67df25d7dceb2f27830483673a9389 https://doi.org/10.1021/ma00070a032 Zobrazit plný text záznamu