Alkene and Alkyne Insertion into Hydrogen-Transition Metal Bonds Catalyzed by Palladium(0) Complex

Autor:	Masafumi Hirano, Kouhei Nakanishi, Ayako Kuramoto, Nobuyuki Komine, Sanshiro Komiya
Rok vydání:	2014
Předmět:	Dimethyl acetylenedicarboxylate chemistry.chemical_classification Ethylene Alkene Markovnikov's rule Alkyne chemistry.chemical_element General Chemistry Photochemistry Catalysis chemistry.chemical_compound chemistry Acetylene Polymer chemistry Ethyl acrylate Palladium
Zdroj:	Topics in Catalysis. 57:960-966
ISSN:	1572-9028 1022-5528
Popis:	Smooth, reversible and Markovnikov selective alkene insertion of ethyl acrylate, acrylonitrile, and ethylene to MHCp(CO)3 (M = Mo, W) or MnH(CO)5 has been catalyzed by Pd(PPh3)4 at 20 °C. Cis-selective insertion of acetylene and dimethyl acetylenedicarboxylate into MHCp(CO)3 (M = Mo, W) also proceeded smoothly.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0a41f0d15acb8f35b73fa281c3f871a3 https://doi.org/10.1007/s11244-014-0258-8 Zobrazit plný text záznamu Plný text ve formátu PDF