Methyl-d3 isotope effects and the origin of α-methyl substituent effects

Autor:	K.L. Servis, D.E. Sunko, S. Borčić
Rok vydání:	1968
Předmět:	chemistry.chemical_compound chemistry Deuterium Computational chemistry Organic Chemistry Drug Discovery Kinetic isotope effect Substituent Organic chemistry Solvolysis Kinetic energy Biochemistry Decomposition
Zdroj:	Tetrahedron. 24:1247-1253
ISSN:	0040-4020
DOI:	10.1016/0040-4020(68)88074-3
Popis:	The kinetic isotope effects on the solvolysis of a series of 1-methyl-d 3 compounds was determined. A linear correspondence between α-methylsubstituent effects and methyl-d 3 isotope effects is presented and discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0a411a8d69bf6ac150f7cef0585a42eb https://doi.org/10.1016/0040-4020(68)88074-3 Zobrazit plný text záznamu