The Influence of Stabilizer on the Formation and Tribotechnical Properties of Cu Nanoparticles
Autor: | Alexander V. Soldatov, A. A. Milov, A. A. Fedotov, Yu. S. Gerasina, M. S. Lipkin, Mikhail A. Soldatov, A. A. Kuzharov, A. S. Kolomiitsev, V. M. Lipkin, I. Yu. Neverov |
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Rok vydání: | 2019 |
Předmět: |
Materials science
food.ingredient 020209 energy Organic Chemistry Metals and Alloys chemistry.chemical_element Nanoparticle 02 engineering and technology Tribology 021001 nanoscience & nanotechnology Copper Gelatin Surfaces Coatings and Films Sodium borohydride chemistry.chemical_compound food chemistry Dynamic light scattering Chemical engineering 0202 electrical engineering electronic engineering information engineering Materials Chemistry Nanotribology 0210 nano-technology Stabilizer (chemistry) |
Zdroj: | Protection of Metals and Physical Chemistry of Surfaces. 55:283-287 |
ISSN: | 2070-206X 2070-2051 |
Popis: | The good wear-resistance of state-of-the-art liquid lubricants is due to the formation of complex metal and organometallic films onto the friction surface, reducing the friction and wear. For this purpose, various additives of metal nanopowders are used, especially ones based on copper. The formation and growth of Cu nanoparticles, as well as the tribotechnical characteristics of lubricants, are mainly affected by the choice of stabilizer, because nanoparticles cannot resist the external conditions without protecting their surface. According to quantum chemical studies, the best stabilizer in the series of gelatin, ammonia, sodium borohydride, and sodium citrate is gelatin due to the very large amount of functional groups in its structure. The characterization of physicochemical properties via dynamic light scattering, atomic force microscopy, and electron microscopy, as well as the tribotechnical characteristics of liquid lubricants with stabilized Cu nanoparticles, are consistent with quantum chemical calculations, confirming that Cu nanoparticles stabilized in gelatin possess the better tribotechnical properties than other stabilizers. |
Databáze: | OpenAIRE |
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