Unusual cleavage of adducts of trialkyl phosphites with perfluoromethacrylic acid derivatives

Autor:	E. I. Mysov, U. Utebaev, E. M. Rokhlin, E. P. Lur'e, I. L. Knunyants
Rok vydání:	1976
Předmět:	chemistry.chemical_classification Chemistry Phosphorus atom General Chemistry Cleavage (embryo) Medicinal chemistry Alkyl Adduct
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 25:853-860
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00922396
Popis:	1. Perfluoromethaerylic acid derivatives when reacted with trialkyl phosphites give stable adducts that contain a pentacoordinated phosphorus atom, and specifically are substitutedα-fluorovinyltrialkoxy-fluorophosphoranes. 2. The phosphoranes obtained from perfluoromethacrylic acid esters and trialkyl phosphites are cleaved when heated, in which connection the products of the Arbuzov reaction are not formed, but instead alkyl difluorophosphites and the esters ofα-trifluoromethyl-β,β-dialkoxyacrylic acids.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0a1a46ef5b64a29aca80e64c23b42098 https://doi.org/10.1007/bf00922396 Zobrazit plný text záznamu Full text from SpringerLink