Coordination nature of phase separation in oxide melts

Autor:	J. Pospekhova, M. Kiselova, Yu. P. Udalov, P. Piluzo, P. Sazavsky, A. Yu. Pechenkov, I. Schrank, Dmitry Grishchenko, I. V. Pozniak
Rok vydání:	2013
Předmět:	Ternary numeral system Inorganic chemistry Iron oxide Oxide chemistry.chemical_element Uranium Condensed Matter Physics Surface tension chemistry.chemical_compound chemistry Materials Chemistry Ceramics and Composites Uranium oxide Cubic zirconia Binary system
Zdroj:	Glass Physics and Chemistry. 39:431-443
ISSN:	1608-313X 1087-6596
DOI:	10.1134/s1087659613040202
Popis:	The behavior of uranium oxide-silica, zirconia-alumina, zirconia-iron oxide, uranium oxideiron oxide, zirconia-alumina-iron oxide, and uranium oxide-iron oxide-zirconia melts was experimentally investigated in the air. The existence of two-phase fluids in these systems was confirmed. It is proposed that the reason for the phase separation is the formation of complexes with the general formula x[M3+O8/2] [Me4+O8/2]. The influence of a complex concentration on the density and surface tension of melts in the ZrO2-Al2O3 system was demonstrated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::09fb085052d9b198ec5d01cd6889a397 https://doi.org/10.1134/s1087659613040202 Zobrazit plný text záznamu Full text from SpringerLink