Electron/Ion Transport Enhancer in High Capacity Li-Ion Battery Anodes
| Autor: | Esther S. Takeuchi, Elsa Reichmanis, Krysten Minnici, Amy C. Marschilok, Kenneth J. Takeuchi, Matthew M. Huie, Yo-Han Kwon |
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| Rok vydání: | 2016 |
| Předmět: |
Materials science
General Chemical Engineering Inorganic chemistry Oxide Nanoparticle 02 engineering and technology General Chemistry Polyethylene glycol 010402 general chemistry 021001 nanoscience & nanotechnology Electrochemistry 01 natural sciences 0104 chemical sciences Electrochemical cell Ion chemistry.chemical_compound chemistry Electrode Materials Chemistry Ionic conductivity 0210 nano-technology |
| Zdroj: | Chemistry of Materials. 28:6689-6697 |
| ISSN: | 1520-5002 0897-4756 |
| DOI: | 10.1021/acs.chemmater.6b02982 |
| Popis: | Magnetite (Fe3O4) was used as a model high capacity metal oxide active material to demonstrate advantages derived from consideration of both electron and ion transport in the design of composite battery electrodes. The conjugated polymer, poly[3-(potassium-4-butanoate) thiophene] (PPBT), was introduced as a binder component, while polyethylene glycol (PEG) was coated onto the surface of Fe3O4 nanoparticles. The introduction of PEG reduced aggregate size, enabled effective dispersion of the active materials and facilitated ionic conduction. As a binder for the composite electrode, PPBT underwent electrochemical doping which enabled the formation of effective electrical bridges between the carbon and Fe3O4 components, allowing for more efficient electron transport. Additionally, the PPBT carboxylic moieties effect a porous structure, and stable electrode performance. The methodical consideration of both enhanced electron and ion transport by introducing a carboxylated PPBT binder and PEG surface treatment l... |
| Databáze: | OpenAIRE |
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