Problem of Loss of Active Metal in the Process of SC–CO2 Extractional Regeneration of the Hydrocleaning Catalyst
Autor: | F. M. Gumerov, T. R. Bilalov |
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Rok vydání: | 2019 |
Předmět: |
inorganic chemicals
010304 chemical physics Chemistry organic chemicals Nickel oxide 010402 general chemistry 01 natural sciences Supercritical fluid 0104 chemical sciences Catalysis Solvent Metal Chemical engineering visual_art Scientific method 0103 physical sciences visual_art.visual_art_medium Physical and Theoretical Chemistry Dissolution Hydrodesulfurization |
Zdroj: | Russian Journal of Physical Chemistry B. 13:1160-1163 |
ISSN: | 1990-7923 1990-7931 |
Popis: | — While studying the features of the regeneration of the hydrodesulfurization catalyst DN-3531 in supercritical CO2 media, it was shown that nickel oxide does not dissolve in it. However, for the application of a mixture of CO2 + DMSO (5 wt %) under specified conditions, the dissolution of nickel oxide in supercritical fluid solvents occurs, apparently due to the formation of Ni[DMSO]xOHy complex, which is soluble in the supercritical fluid solvent mixture. |
Databáze: | OpenAIRE |
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