A perfluorometallacycloheptane complex of nickel bipyridine
| Autor: | David A. Vicic, Katherine R. McGarry |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
010405 organic chemistry
Organic Chemistry Inorganic chemistry chemistry.chemical_element Metallacycle 010402 general chemistry 01 natural sciences Biochemistry 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound Bipyridine Nickel Crystallography chemistry Yield (chemistry) Fluorine Environmental Chemistry Physical and Theoretical Chemistry Organometallic chemistry |
| Zdroj: | Journal of Fluorine Chemistry. 203:206-209 |
| ISSN: | 0022-1139 |
| DOI: | 10.1016/j.jfluchem.2017.03.007 |
| Popis: | Reaction of [(bpy)NiEt2] with 1,6-dibromododecafluorohexane in THF at room temperature led to [(bpy)Ni(η2-C,C-C6F12)] (1) in 13% isolated yield. Compound 1 represents the first example of a perfluorinated metallacycloheptane and a rare example of an isolable metallacycloheptane in general. X-ray diffraction studies confirmed the structure of 1. Key nickel bond distances, in A, are: Ni-C6 1.903(9); Ni-C1 1.925(10); Ni-N1 2.004(7); Ni-N2 2.011(8). |
| Databáze: | OpenAIRE |
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