Chiral recognition of odorants (+)- and (-)-carvone by phospholipid monolayers
| Autor: | William C. Neely, Lawrence J. Myers, Suram T. Pathirana, Vitaly Vodyanoy |
|---|---|
| Rok vydání: | 1992 |
| Předmět: |
Carvone
Stereochemistry technology industry and agriculture Phospholipid General Chemistry Atmospheric temperature range Surface pressure Biochemistry Catalysis chemistry.chemical_compound Crystallography Colloid and Surface Chemistry chemistry Phosphatidylcholine Monolayer lipids (amino acids peptides and proteins) |
| Zdroj: | Journal of the American Chemical Society. 114:1404-1405 |
| ISSN: | 1520-5126 0002-7863 |
| DOI: | 10.1021/ja00030a041 |
| Popis: | Interactions of the odorants (+)- and (-)-carvone with L-α-1,2-dipalmitoyl-sn-glycero-3-phosphocholine (L-DPPC) monolayers were studied using surface pressure and surface potential versus area isotherms measured in the temperature range 10-35 o C in the presence and absence of 5 mM odorants in the subphase. The data indicate that the L-DPPC monolayers with (-)-carvone absorb twice as much heat as those with (+)-carvone when compressed at 30 o C. Under the same conditions, monolayers with (-)-carvone undergo a larger entropy change than monolayers with (+)-carvone |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|