Synthesis of new mer,trans-rhodium(III) hydrido-bis(acetylide) complexes: Structure of mer,trans-[(PMe3)3Rh(CC–C6H4-4-NMe2)2H]

Autor:	Wai-Kwok Wong, Richard M. Ward, Paul J. Low, Judith A. K. Howard, David Albesa-Jové, Todd B. Marder, Xun-Jin Zhu, Laurent Porrès, Andrew Beeby
Rok vydání:	2006
Předmět:	Ligand Hydride Stereochemistry Acetylide chemistry.chemical_element Crystal structure Rhodium Inorganic Chemistry chemistry.chemical_compound chemistry Transition metal Materials Chemistry Molecule Physical and Theoretical Chemistry Derivative (chemistry)
Zdroj:	Inorganica Chimica Acta. 359:2859-2863
ISSN:	0020-1693
DOI:	10.1016/j.ica.2005.11.030
Popis:	Terminal alkynes (R–C C–H, R = 1-naphthyl, 9-anthryl, 4-Me2N–C6H4–, or the longer analogue, 4-(4-Me2N–C6H4–C C–)–C6H4–) react with [Rh(PMe3)4Me] at ambient temperature, with loss of methane and one PMe3 ligand, to form the corresponding mer,trans-[(PMe3)3Rh(C CR)2H] compounds in excellent yield. In this preliminary study, the synthesis and spectroscopic characterization of the four new compounds are reported, along with the single-crystal structure of the R = 4-Me2N–C6H4 derivative.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0999d45b4d934bb3d2d7ab99e2173871 https://doi.org/10.1016/j.ica.2005.11.030 Zobrazit plný text záznamu Full Text from ScienceDirect