ChemInform Abstract: A New and Versatile Diamide-Diamine Donor Ligand Set in Early Transition Metal Chemistry

Autor:	Philip Mountford, Michael E. G. Skinner, David A. Cowhig
Rok vydání:	2000
Předmět:	chemistry.chemical_compound Transition metal Ligand Chemistry Diamine Polymer chemistry Alkoxide Cationic polymerization General Medicine
Zdroj:	ChemInform. 31
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200041111
Popis:	Straightforward, multigram synthesis of the new diamide–diamine proligand H2N2NN′ [N2NN′ = (2-NC5H4)CH2N(CH2CH2 NSiMe3)2] is described along with a preliminary survey of the five- and six-coordinate, neutral and cationic, single- and multiply-bonded complexes of groups 3, 4 and 5 that it can support; the related bis(alkoxide)–diamine proligand H2O2NN′ is also described where H2O2NN′ = (2-NC5H4)CH2N(CH2CMe2 OH)2.
Databáze:	OpenAIRE
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