Synthesis of Group 1 Metal 2,6-Diphenylphenoxide Complexes [M(OC6H3Ph2-2,6)] (M = Li, Na, K, Rb, Cs) and Structures of the Solvent-Free Complexes [Rb(OC6H3Ph2-2,6)]x and [Cs(OC6H3Ph2-2,6)]x: One-Dimensional Extended Arrays of Metal Aryloxides

Autor:	Ian P. Rothwell, Phillip E. Fanwick, Charles S. Weinert
Rok vydání:	2003
Předmět:	Solvent free Chemistry Stereochemistry Coordination number Solid-state Inorganic Chemistry Bridging oxygen Metal Crystallography chemistry.chemical_compound Group (periodic table) visual_art Yield (chemistry) visual_art.visual_art_medium Physical and Theoretical Chemistry Benzene
Zdroj:	Inorganic Chemistry. 42:6089-6094
ISSN:	1520-510X 0020-1669
Popis:	Reaction of 2,6-diphenylphenol (HOC6H3Ph2-2,6) with nBuLi, NaH, KH, or Rb or Cs metal in benzene gives the solvent-free complexes [M(OAr)]x in excellent yield. The complex [Rb(OC6H3Ph2-2,6)]x exhibits a ladderlike structure in the solid state with triply bridging oxygen atoms and Rb−O distances of 2.743(3), 2.930(2), and 2.973(2) A. The Rb cations interact with the π-electron cloud of the arene moieties, giving rise to a high Rb coordination number. The cesium-containing congener forms a layered, columnlike structure consisting of [Cs2(μ2-OAr)2] units, with nearly identical Cs−O distances of 2.945(2) and 2.947(2) A. The individual layers are held together solely by Cs−arene π-interactions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0966f4d2d0eb1891aed350c95b72e28e https://doi.org/10.1021/ic0346580 Zobrazit plný text záznamu