Exact Uniqueness and Multiplicity Criteria For a Class of Lumped Reaction Systems

Autor:	T.T. Tsotsis, Roger A. Schmitz, A.E. Haderi
Rok vydání:	1982
Předmět:	Exothermic reaction Applied Mathematics General Chemical Engineering Mathematical analysis Of the form General Chemistry Uniqueness Parameter space Multiplicity (chemistry) Endothermic process Industrial and Manufacturing Engineering Isothermal process Mathematics
Zdroj:	Chemical Engineering Science. 37:1235-1243
ISSN:	0009-2509
DOI:	10.1016/0009-2509(82)85066-5
Popis:	Steady-State multiplicity and uniqueness criteria are derived for a rather general lu ped model of chemically reacting systems for which reaction-rate expressions are of the form Kc p e -E a /R g T / (1 + lc ) a . Application of the criteria involves relatively simple calculations and leads to an exact description of the steady-state pattern in parameter space. The general results are summarized in the form of computational flow charts and employed in a study of the particular case of a bimolecular reaction of the Langmuir-Hinshelwood type. In certain situations with q > p, there esist five steady-states for exothermic reactions and three for endothermic or isothermal reactions.
Databáze:	OpenAIRE
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