Formal Aryne/Carbon Monoxide Copolymerization To Form Aromatic Polyketones/Polyketals

Autor:	Katsuyuki Nishimura, Kyoko Nozaki, Shingo Ito, Wenhan Wang
Rok vydání:	2015
Předmět:	chemistry.chemical_classification Polymers and Plastics Organic Chemistry Monoxide Polymer Aryne Inorganic Chemistry chemistry.chemical_compound chemistry Polymer chemistry Materials Chemistry Copolymer Organic chemistry Carbon monoxide
Zdroj:	Macromolecules. 48:1959-1962
ISSN:	1520-5835 0024-9297
DOI:	10.1021/acs.macromol.5b00315
Popis:	A palladium-catalyzed alternating copolymerization of [2.2.1]oxabicyclic alkenes 1 with carbon monoxide afforded isomer mixtures of polyketones 2ktn and polyketals 2ktl. Subsequent acid-induced dehydration of polymer 2 furnished novel aromatic polymers consisting of polyketones 3ktn and polyketals 3ktl units. This formal aryne/carbon monoxide copolymerization thus generated the first example of poly(aryne-alt-carbon monoxide)s, in which o-arylene and carbonyl units are incorporated in an alternating fashion.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::096362b7a7b7ca3555f10ecaa768b6f1 https://doi.org/10.1021/acs.macromol.5b00315 Zobrazit plný text záznamu