Phase transfer catalysis in the tert-butyloxycarbonylation of alcohols, phenols, enols, and thiols with di-tert-butyl dicarbonate

Autor:	Jean M. J. Fréchet, C. G. Willson, Francine Bouchard, Francis M. Houlihan
Rok vydání:	1985
Předmět:	Organic Chemistry General Chemistry Di-tert-butyl dicarbonate Enol Catalysis chemistry.chemical_compound chemistry Organic chemistry Phenol Phenols Dicarbonate Aliphatic compound Protecting group
Zdroj:	Canadian Journal of Chemistry. 63:153-162
ISSN:	1480-3291 0008-4042
Popis:	It is shown that the tert-butyloxycarbonylation of phenols, alcohols, enols, and thiols can be accomplished by reaction of these functionalities with di-tert-butyl dicarbonate under phase transfer conditions. The reactions proceed in high yield and can also be used for the introduction of t-BOC groups onto functionalized polymer backbones such as novolac or poly(p-hydroxystyrene). In addition, a study is made of the selectivity towards tert-butyloxycarbonylation of various polyfunctional compounds.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::095f154293064ce5c0ad4c403d504fce https://doi.org/10.1139/v85-025 Zobrazit plný text záznamu