Strong Influence of the Nucleophile on the Rate and Selectivity of 1,2-Epoxyoctane Ring Opening Catalyzed by Tris(pentafluorophenyl)borane, B(C6F5)3
| Autor: | Linda J. Broadbelt, Mihir N. Bhagat, Youlong Zhu, SonBinh T. Nguyen, Justin M. Notestein, Charmaine K. Bennett, Matthew E. Belowich, Ying Yu, Arjun Raghuraman |
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| Rok vydání: | 2019 |
| Předmět: |
inorganic chemicals
Tris Reaction mechanism 010405 organic chemistry General Chemistry 010402 general chemistry 01 natural sciences Medicinal chemistry Catalysis 0104 chemical sciences chemistry.chemical_compound chemistry Nucleophile Tris(pentafluorophenyl)borane Density functional theory Lewis acids and bases Selectivity |
| Zdroj: | ACS Catalysis. 9:11589-11602 |
| ISSN: | 2155-5435 |
| Popis: | Density functional theory (DFT) calculations, experimental data, and microkinetic modeling are used to extend a triple-pathway (Lewis acid, water-mediated, and alcohol-mediated) mechanism for tris(... |
| Databáze: | OpenAIRE |
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