Preparation of selenofunctionalized heterocycles via iodosobenzene-mediated intramolecular selenocyclizations of olefins with diselenides
| Autor: | Wei Yi, Liang Ming, Yong Ling, Yu Zhao, Gong-Qing Liu, Peng-Fei Wang |
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| Rok vydání: | 2021 |
| Předmět: |
Reaction conditions
Iodosobenzene Hypervalent molecule 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Combinatorial chemistry 0104 chemical sciences chemistry.chemical_compound chemistry Intramolecular force Reagent Functional group Surface modification Molecule 0210 nano-technology |
| Zdroj: | Chinese Chemical Letters. 32:2587-2591 |
| ISSN: | 1001-8417 |
| Popis: | An intramolecular selenocyclizations of olefins mediated by a commercially available hypervalent iodine(III) reagent, PhIO, was developed. This method provided access to a wide range of selenenylated heterocycles under ambient conditions. The striking advantages of this protocol over all previous methods include mild reaction conditions, easy operation, good yields, high levels of functional group compatibility, large–scale application and suitability for the late-stage functionalization of complex molecules of biological importance. |
| Databáze: | OpenAIRE |
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