Synthesis and Single-Crystal X-ray Diffraction Examination of a Structurally Homologous Series of Tetracoordinate Heteroleptic Anionic Lanthanide Complexes: Ln{N[Si(CH3)2CH2CH2Si(CH3)2]}3(μ-Cl)Li(L)3 [Ln = Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb; (L)3 = (THF)3, (Et2O)3, (THF)2(Et2O)]

Autor:	Oliver Just, William S. Rees
Rok vydání:	2001
Předmět:	Lanthanide Tetracoordinate chemistry.chemical_element Inorganic Chemistry Homologous series chemistry.chemical_compound Crystallography Monomer chemistry X-ray crystallography Melting point Lithium Physical and Theoretical Chemistry Single crystal
Zdroj:	Inorganic Chemistry. 40:1751-1755
ISSN:	1520-510X 0020-1669
Popis:	Anhydrous lanthanide(III) chlorides (Ln = Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb) react with 3 equiv of lithium 2,2,5,5-tetramethyl-2,5-disila-1-azacyclopentanide, Li[N[Si(CH3)2CH2Ch2Si(CH3)2]], in THF or Et(2)O to afford the monomeric four-coordinate heteroleptic ate complexes Ln[N[Si(CH3)2CH2CH2Si(CH3)2]]3(mu-Cl)Li(THF/Et2O)3 (Ln = Sm (1), Eu (2), Gd (3), Tb (4), Dy (5), Ho (6), Er (7), Tm (8), Yb (9)), whose solid-state structures were determined by the single-crystal X-ray diffraction technique. All complexes additionally were characterized by melting point determination, elemental analyses, and mass spectrometry.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::0952c9e3add4a25b95daadc5c60ceff9 https://doi.org/10.1021/ic9912023 Zobrazit plný text záznamu