Kinetic Evidence for π-Complex Formation Prior to Oxidative Addition of Propargyl Halides to Triphenylphosphine−Platinum(0) Complexes

Autor:	Hideo Kurosawa, Ken Tsutsumi, Sensuke Ogoshi, Takuma Nishida, and Yoshiaki Fukunishi
Rok vydání:	2000
Předmět:	Organic Chemistry Kinetics Complex formation chemistry.chemical_element Halide Photochemistry Kinetic energy Medicinal chemistry Oxidative addition Inorganic Chemistry chemistry.chemical_compound chemistry Propargyl Physical and Theoretical Chemistry Triphenylphosphine Platinum
Zdroj:	Organometallics. 19:4488-4491
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om000376l
Popis:	The mechanism of oxidative addition of phenylpropargyl halides to Pt(PPh3)4 to give Pt(η1-CH2C⋮CPh)(X)(PPh3)2 has been investigated on the basis of the kinetics of the reaction and stereomeric anal...
Databáze:	OpenAIRE
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