Dewetting Behavior of Hydrogen Bonded Polymer Complex Film under Hydrothermal Condition
| Autor: | Gengxin Liu, Shuguang Yang, Song-Mei Ma, Chao Su |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
chemistry.chemical_classification
Materials science Polymers and Plastics Hydrogen Hydrogen bond Infrared General Chemical Engineering Organic Chemistry chemistry.chemical_element 02 engineering and technology Polymer 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Hydrothermal circulation 0104 chemical sciences chemistry.chemical_compound symbols.namesake chemistry Chemical engineering symbols Dewetting 0210 nano-technology Raman spectroscopy Acrylic acid |
| Zdroj: | Chinese Journal of Polymer Science. 36:1036-1042 |
| ISSN: | 1439-6203 0256-7679 |
| Popis: | Hydrogen-bonded polymer complex films with the thickness ranging from 50 nm to 2400 nm were prepared by layer-by-layer (LbL) assembly of poly(2-ethyl-2-oxazoline) (PEOX) and poly(acrylic acid) (PAA). The dewetting behavior of PEOX/PAA films under hydrothermal condition was investigated. It was found that the dewetting occurred at solid-liquid interface, and the typical morphologies such as holes, irregular cellular structure, and droplets were observed. Atomic force microscopy (AFM) revealed the initial rupture of the film. Microscopic Raman and infrared (IR) imaging demonstrated that the PEOX and PAA chains remained association during the dewetting process. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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