Efficient Tosylation of Dihydroxybenzenes in a Two-Phase Water–Dichloromethane System
| Autor: | V. I. Rybachenko, V. N. Anishchenko, A. N. Red’ko |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
chemistry.chemical_classification
Base (chemistry) 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Catalysis Potassium carbonate Reaction rate chemistry.chemical_compound chemistry Phase (matter) Yield (chemistry) Pyridine Organic chemistry 0210 nano-technology Dichloromethane |
| Zdroj: | Theoretical and Experimental Chemistry. 56:46-49 |
| ISSN: | 1573-935X 0040-5760 |
| DOI: | 10.1007/s11237-020-09639-1 |
| Popis: | The effect of the structure of the catalyst and the type of base on the reaction rate and product yield of the tosylation of dihydroxybenzenes in a two-phase water–dichloromethane system in the presence of pyridine N-oxide derivatives was demonstrated. It was found that with 4-dimethylaminopyridine N-oxide and potassium carbonate it is possible to obtain dihydroxybenzene tosylates with yields of more than 90%. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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