Nuclear magnetic resonance of pretransitional ordering of liquid crystals in well defined nano-geometries: the utility of the Landau–de Gennes formalism

Autor:	Gregor Skačej, Slobodan Žumer, Sylvain G. Cloutier, Xin Ma, Ichiro Amimori, Renate J. Crawford, Gregory P. Crawford
Rok vydání:	2009
Předmět:	Phase transition Formalism (philosophy of mathematics) Nuclear magnetic resonance Materials science Deuterium Condensed matter physics Liquid crystal Nano General Materials Science General Chemistry Well-defined Condensed Matter Physics Mathematics::Numerical Analysis
Zdroj:	Liquid Crystals. 36:1229-1240
ISSN:	1366-5855 0267-8292
DOI:	10.1080/02678290903059263
Popis:	The Landau–de Gennes (LdG) formalism has had a significant impact in many areas of physics and perhaps arguably most of all in understanding liquid crystals. In this review, we treat the utility of the LdG formalism in studying the ordering of liquid crystal systems confined at the nanoscale. The LdG formalism describes surface-induced ordering phenomena above the second-order phase transition point and predicts the disappearance of the nematic–isotropic transition into a continual evolution of order under certain conditions. We focus this paper on how the LdG theory has been used to understand ordering in well-defined nanoscaled environments, such as cylinders and ellipsoidal droplets, using deuterium nuclear magnetic resonance (2H-NMR) to probe the evolution of order as it develops above the isotropic–nematic transitions and through the transition itself.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::093f5a584929d0a98dce8043ac519bb7 https://doi.org/10.1080/02678290903059263 Zobrazit plný text záznamu