Determination of the structures of esters of polybranched monocarboxylic acids by13C NMR spectroscopy

Autor:	V. I. Dostovalova, R. Kh. Freidlina, M. A. Moskalenko, N. S. Ikonnikov, A. B. Tarent'ev
Rok vydání:	1980
Předmět:	NMR spectra database Isovalerate chemistry.chemical_compound Ethylene chemistry Carbon-13 NMR satellite Telomerization Polymer chemistry Organic chemistry Molecule General Chemistry Nuclear magnetic resonance spectroscopy Fluorine-19 NMR
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 29:377-382
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00949620
Popis:	1. The13C NMR spectra of esters of polybranched acids contain characteristic signals of COO, CH3, and CH groups that are sensitive to theβ andγ effects of substituents, and this makes it possible to use the data from the13C NMR spectra to establish the structures of complex molecules. 2. The telomerization of ethylene by methyl isovalerate proceeds with cleavage of the C-H bond in both theα-CH2 andβ-CH groups.
Databáze:	OpenAIRE
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