Different functional groups modified porous organic polymers used for low concentration CO2 fixation
| Autor: | Jindong Yuan, Jinzhong Yao, Yuanfei Bao, Zhifeng Dai, Yubing Xiong |
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| Rok vydání: | 2021 |
| Předmět: |
chemistry.chemical_classification
Carbon fixation Metals and Alloys General Chemistry Polymer Catalysis Cycloaddition Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound Chemical engineering chemistry Ionic liquid Materials Chemistry Ceramics and Composites Selectivity Porosity Volume concentration |
| Zdroj: | Chemical Communications. 57:9732-9735 |
| ISSN: | 1364-548X 1359-7345 |
| Popis: | Through a facile post-synthetic method, different kinds of polar group-functionalized ionic liquid porous organic polymers (POP-PA-COOH, POP-PA-OH, and POP-PA-NH2) were obtained. The materials can be used as efficient heterogeneous catalysts in the cycloaddition reaction of CO2 with epoxides under mild and co-catalyst-free conditions. It is demonstrated that POP-PA-NH2 possesses much higher catalytic activity than POP-PA-OH and POP-PA-COOH. Interestingly, this activity difference can further be amplified when the reaction is carried out under low CO2 concentration, and POP-PA-NH2 possesses a conversion of 84.7% with a selectivity of 99.0% in 96 h. It is noteworthy to mention that research focusing on the transformation of CO2 under low concentration using heterogeneous catalysts is rare and still a challenge. The excellent activities of POP-PA-NH2 under low CO2 concentration make this material a good candidate for CO2 elimination under mild conditions. |
| Databáze: | OpenAIRE |
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