Synthesis and Crystal Structure of Cadmium(II) Metal-Organic Coordination Polymers with Octafluorobiphenyl-4,4'-Dicarboxylate
| Autor: | Denis G. Samsonenko, A. M. Cheplakova, Andrey S. Vinogradov, Vladimir P. Fedin, V. S. Gusarov |
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| Rok vydání: | 2021 |
| Předmět: |
chemistry.chemical_classification
Coordination polymer Materials Science (miscellaneous) Crystal structure Polymer Inorganic Chemistry Metal Solvent chemistry.chemical_compound Dicarboxylic acid chemistry visual_art Polymer chemistry visual_art.visual_art_medium Molecule Methanol Physical and Theoretical Chemistry |
| Zdroj: | Russian Journal of Inorganic Chemistry. 66:1374-1379 |
| ISSN: | 1531-8613 0036-0236 |
| Popis: | The reaction between equimolar amounts of Cd(OH)2 and octafluorobiphenyl-4,4'-dicarboxylic acid H2oFBPDC in methanol at 40 and 70°С has been investigated. Two new metal-organic coordination polymers have been obtained and structurally characterized, namely chain-like [Cd3(CH3OH)10(oFBPDC)3]⋅2CH3OH (I) and layered [Cd(CH3OH)3(oFBPDC)] (II). It is shown that the increase of the temperature of the synthesis leads to the formation of coordination polymer of higher dimensionality with less amount of guest and coordinated solvent molecules. |
| Databáze: | OpenAIRE |
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