Halogenation of quaternary phosphonium salts containing prop-1(2)-enyl group
| Autor: | L. V. Derdzyan, G. A. Gasparyan, R. А. Tamazyan, А. S. Bichakhchyan, M. Zh. Ovakimyan, А. G. Haivazyan, R. R. Bagratyan |
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| Rok vydání: | 2017 |
| Předmět: |
chemistry.chemical_classification
Double bond 010405 organic chemistry Halogenation General Chemistry 010403 inorganic & nuclear chemistry 01 natural sciences Medicinal chemistry humanities 0104 chemical sciences Adduct chemistry.chemical_compound stomatognathic system chemistry Group (periodic table) Bromide Organic chemistry Phosphonium |
| Zdroj: | Russian Journal of General Chemistry. 87:1727-1730 |
| ISSN: | 1608-3350 1070-3632 |
| DOI: | 10.1134/s1070363217080151 |
| Popis: | Bromination of prop-2-enyltributyl- and -triphenylphosphonium bromides affords the products of addition to the double bond. The structure of the triphenylphosphonium adduct was established by X-ray diffraction analysis. The latter is formed also by radical bromination of prop-1-enyltriphenylphosphonium bromide. The chlorination of prop-1- and 2-enyltriphenylphosphonium bromides leads to the formation of 3-chloroprop-1-enyltriphenylphosphonium bromide. |
| Databáze: | OpenAIRE |
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