Small molecular host based on carbazole and m-terphenyl derivatives for efficient solution processed organic light-emitting diodes

Autor: Akihide Kitamura, Dong Ryeol Hwang, Xu Lin, Young-Seo Park, Jang-Joo Kim, Takashi Karatsu, Soo Young Park, Shiki Yagai
Rok vydání: 2012
Předmět:
Zdroj: Synthetic Metals. 162:303-308
ISSN: 0379-6779
DOI: 10.1016/j.synthmet.2011.12.010
Popis: Two soluble phosphorescent host materials, 1,4-bis(3,6-di([1,1′:3′,1″:3″,1‴:3‴,1⁗-quinquephenyl]-5″-yl)-9 H -carbazol-9-yl)benzene (P-mPCCP) and 1,4-bis(3,6-bis(4,4″-di-tert-butyl-[1,1′:3′,1″-terphenyl]-5′-yl)-9 H -carbazol-9-yl) benzene (T-mPCCP) derived form carbazole and m -terphenyl derivatives were designed and synthesized. These two hosts exhibit good solubility in common organic solvents and possess high glass transition temperature ( T g > 160 °C) and thermal stability. P-mPCCP and T-mPCCP as the host materials doped with the guest of fac -Ir(ppy) 3 , we fabricated phosphorescent organic light emitting diodes (PHOLED) by spin coating process. The turn-on voltage of P-mPCCP and T-mPCCP composing device was 4.0 and 7.0 eV and showed a maximum luminance of 21,100 and 3290 cd/m 2 and a maximum luminance efficiency of 15.0 and 7.6 cd/A, respectively.
Databáze: OpenAIRE