An NMR study of the structures of lanthanide diethylenetriaminepentaacetates

Autor: A. A. Cherepanov, T. P. Klimova, Yu. V. Gol’tyapin, V. N. Kulakov, A. A. Lipengol’ts, T. A. Babushkina, Alexander S. Peregudov
Rok vydání: 2015
Předmět:
Zdroj: Russian Journal of Coordination Chemistry. 41:43-46
ISSN: 1608-3318
1070-3284
Popis: The paramagnetic chemical shifts in the 1H and 13C NMR spectra of lanthanide complexes (Ln = Eu, Yb, and Pr) with diethylenetriaminepentaacetic acid were analyzed. It was demonstrated that Eu+3 in aqueous solution can coordinate to one of the carboxylate groups in a chelating bidendate fashion through two O atoms.
Databáze: OpenAIRE