Coordination Copolymerization of Butadiene with Polar Diene Monomers Based on Myrcene

Autor:	M. S. Chinova, G. R. Khusainova, Andrei V. Shlyakhtin, I. F. Gavrilenko, A. M. Vagizov, N. N. Kostitsyna, S. A. Korchagina, Ilya E. Nifant'ev, A. N. Tavtorkin
Rok vydání:	2018
Předmět:	010407 polymers Polymers and Plastics Diene 010402 general chemistry Microstructure 01 natural sciences 0104 chemical sciences Catalysis chemistry.chemical_compound Monomer chemistry Myrcene Polymer chemistry Halogen Materials Chemistry Ceramics and Composites Copolymer Polar
Zdroj:	Polymer Science, Series B. 60:699-707
ISSN:	1555-6123 1560-0904
DOI:	10.1134/s1560090418060118
Popis:	The synthesis of myrcene-based polar monomers containing substituents of types halogen, SR, NR2, and OR along with the diene fragment is developed. It is shown that these monomers are involved in the coordination copolymerization with butadiene catalyzed by neodymium compounds. The molecularmass characteristics of these copolymers and their microstructure are studied. The method proposed for the synthesis of functional monomers based on large-tonnage natural raw material (turpentine) makes them available and promising for industrial use in the synthesis of diene rubbers.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::08f8e92d0f1391f3bb32ebbe19642a84 https://doi.org/10.1134/s1560090418060118 Zobrazit plný text záznamu Full text from SpringerLink