PtCl2 mediated peripheral transformation of carbatriphyrin(3.1.1) into a meso-fused β–β′ dimer and its monomer analogue
| Autor: | Mainak Das, S. Peruncheralathan, B. Adinarayana, Muthuchamy Murugavel, Alagar Srinivasan, Narasinga Rao Palepu |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
chemistry.chemical_classification
Ligand Stereochemistry Dimer Metals and Alloys Salt (chemistry) Single step General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound Transformation (genetics) Monomer chemistry Materials Chemistry Ceramics and Composites |
| Zdroj: | Chemical Communications. 56:12809-12812 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/d0cc05309k |
| Popis: | An unprecedented formation of a meso-fused β–β′ carbaporphyrin dimer and its monomer with a keto group was described. These analogues were synthesized from carbatriphyrin(3.1.1.) by a metal assisted strategy using PtCl2 salt in a single step without any prefunctionalized precursors. Upon dimerization, the monomeric ligand with a dianionic core is transformed into a dimeric structure with unique trianionic cores. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|