The synthesis of garugamblin-1

Autor: György M. Keserü, Gabriella Mezey-Vándor, Borbála Vermes, Gábor Tóth, Mihály Nógrádix
Rok vydání: 1993
Předmět:
Zdroj: Tetrahedron. 49:4893-4900
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(01)80406-3
Popis: The Z isomer of the title compound (21) and its regioisomer (22) were synthesized using an isoxazole synthon (17) for the elaboration of the β-methoxy-enone function. 21 and 20 spontaneously isomerized to the E isomers i.e. to garugamblin-1 (1) and its regioisomer (22) resp.
Databáze: OpenAIRE