The synthesis of garugamblin-1
Autor: | György M. Keserü, Gabriella Mezey-Vándor, Borbála Vermes, Gábor Tóth, Mihály Nógrádix |
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Rok vydání: | 1993 |
Předmět: | |
Zdroj: | Tetrahedron. 49:4893-4900 |
ISSN: | 0040-4020 |
DOI: | 10.1016/s0040-4020(01)80406-3 |
Popis: | The Z isomer of the title compound (21) and its regioisomer (22) were synthesized using an isoxazole synthon (17) for the elaboration of the β-methoxy-enone function. 21 and 20 spontaneously isomerized to the E isomers i.e. to garugamblin-1 (1) and its regioisomer (22) resp. |
Databáze: | OpenAIRE |
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