Method of preparation of alkylated 1,3-diphenylpropan-2-ones, the components for assembly of graphene nanostructures

Autor:	Yu. A. Ten, N. M. Troshkova, E. V. Tretyakov
Rok vydání:	2020
Předmět:	Nanostructure Graphene General Chemistry Alkylation Combinatorial chemistry law.invention chemistry.chemical_compound Hydrolysis chemistry Quantum dot law Dioxolane Magnesium bromide Graphene nanoribbons
Zdroj:	Russian Chemical Bulletin. 69:172-175
ISSN:	1573-9171 1066-5285
Popis:	Long-chain alkylated 1,3-diphenyl-2-propanones are used in the synthesis of graphene nanostructures (graphene nanoribbons and quantum dots). A reliable procedure to obtain mono- or dialkylated diphenyl-2-propanones in 26 and 38% yields has been proposed. The method includes the dioxolane protection of the keto group in 1,3-di-(4-bromophenyl)-2-propanone, then a palladium-catalyzed cross-coupling reaction of the obtained dioxolane with one-and-a-half- or four-fold excess of dodecyl magnesium bromide that leads to a predominant formation of mono- or dialkylation products respectively, followed by hydrolysis of dioxolanes at the last stage to form the desired diphenyl-2-propanones.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::08b66ab26d657e109ed0c5e8c991452a https://doi.org/10.1007/s11172-020-2740-8 Zobrazit plný text záznamu Full text from SpringerLink