On the reaction of methyl dichlorophosphine with acrylamide
Autor: | A. N. Pudovik, R. M. Kondrat'eva, V. K. Khairullin |
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Rok vydání: | 1967 |
Předmět: | |
Zdroj: | Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 16:2019-2021 |
ISSN: | 1573-9171 0568-5230 |
DOI: | 10.1007/bf00909610 |
Popis: | 1. The following compounds are formed by the reaction of methyl dichlorophosphine with acrylamide: methyl-β-cyanoethylphosphonyl chloride (36.6%),β-chloropropionitrile (16.2%) and methyl-β-cyanoettylphosphonic acid (3.4%). 2. The reaction of methyl-β-cyanoethylphosphonyl chloride with water (2∶1) gave methyl-β-cyanoethylphosphonic acid anhydride. 3. By reacting methyl-β-cyanoethylphosphonyl chloride with alcohols and diethylamine, we have obtained a number of esters and the diethylamide of methyl-β-cyanoethylphosphonic acid. |
Databáze: | OpenAIRE |
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