STUDIES ON COMPLEXES OF COBALT(II), NICKEL(II), COPPER(II), AND CADMIUM(II) WITH ACETOPHENONE AND 4-HYDROXYACETOPHENONE OXALOYLDIHYDRAZONES
| Autor: | Bachcha Singh, Krishan K. Narang, Rachana Srivastava |
|---|---|
| Rok vydání: | 2001 |
| Předmět: |
Cadmium
biology Aspergillus niger Inorganic chemistry chemistry.chemical_element biology.organism_classification Magnetic susceptibility Copper Inorganic Chemistry chemistry.chemical_compound Nickel chemistry Physical and Theoretical Chemistry Cobalt Powder diffraction Acetophenone Nuclear chemistry |
| Zdroj: | Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 31:1387-1401 |
| ISSN: | 1532-2440 0094-5714 |
| DOI: | 10.1081/sim-100107205 |
| Popis: | The complexes [M(L1)nCl2] and [Cu(L2)SO4(H2O)2] [M= Co(II), Ni(II), Cu(II) and Cd(II); L1=acetophenone oxaloyldihydrazone (CONHN═C(CH3)C6H5)2, n=2 and L2=4-hydroxyacetophenone oxaloyldihydrazone (CONHN= C(CH3)C6H4OH–4)2 have been prepared. Analytical, molar conductance, magnetic susceptibility, electronic, ESR and NMR spectral data have been used to investigate the structure and bonding of the complexes. X-ray powder diffraction data indicate the shape and size of the unit cell of the copper(II) complex. Some of the complexes were screened against E. coli and Aspergillus niger for biological activity. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|