The chemistry of vitamin B12. Part XIV. Reaction of vitamin B12s with nitrobenzene and its reduction products

Autor:	R. J. P. Williams, M. P. O'riordan, H. Gott, H. A. O. Hill, J. M. Pratt, A. E. Brearley
Rok vydání:	1971
Předmět:	chemistry.chemical_element Hydroxocobalamin Cobalamin Medicinal chemistry Inorganic Chemistry Nitrosobenzene Nitrobenzene chemistry.chemical_compound Aniline chemistry Azobenzene medicine Organic chemistry Physical and Theoretical Chemistry Phenylhydroxylamine Cobalt medicine.drug
Zdroj:	Journal of the Chemical Society A: Inorganic, Physical, Theoretical. :612
ISSN:	0022-4944
Popis:	The reduction of nitrobenzene, nitrosobenzene, and azoxybenzene by potassium borohydride is catalysed by hydroxocobalamin. The products of the reaction with nitrobenzene include aniline and azobenzene. The cobalt(I) cobalamin, vitamin B12s, reacts with nitrobenzene, nitrosobenzene, azoxybenzene, and azobenzene but not with phenylhydroxylamine or hydrazobenzene. A mechanism for the reduction is proposed.
Databáze:	OpenAIRE
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