ChemInform Abstract: Direct Synthesis of Trisilaalkanes

Autor: Seung-Ho Yeon, Gyu-Hwan Lee, Mi-Yeon Suk, Il Nam Jung
Rok vydání: 2010
Předmět:
Zdroj: ChemInform. 23
ISSN: 0931-7597
DOI: 10.1002/chin.199207213
Popis: A series of trisilaalkanes has been prepared in high yields by the direct reaction of -chloromethylsilanes with metallic silicon in the presence of copper catalyst using the stirred reactor equipped with a spiral band agitator at the carefully controlled temperature between and Disilaalkane compounds were obtained as the minor products. Cadmium was found to be a good promotor for the reactions, while zinc was an inhibitor.
Databáze: OpenAIRE