The synthesis of alkenes from carbonyl compounds and carbanions α to silicon IV. Stereoselective conversion of RCHO into E-RCHCHCH2 Cl

Autor:	Tak Hang Chan, W. Mychajlowskij, B. S. Ong, David N. Harpp
Rok vydání:	1976
Předmět:	Allylic rearrangement Silicon Chemistry Organic Chemistry chemistry.chemical_element Biochemistry Chloride Inorganic Chemistry Materials Chemistry medicine Organic chemistry Stereoselectivity Physical and Theoretical Chemistry medicine.drug Carbanion
Zdroj:	Journal of Organometallic Chemistry. 107:C1-C4
ISSN:	0022-328X
DOI:	10.1016/s0022-328x(00)91783-2
Popis:	The stereochemistry of the allylic rearrangement of (α-trimethylsilylvinyl)carbinyl chloride was investigated. From these results, a method for the stereoselective conversion of RCHO into E-RCH=CHCH2Cl was proposed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::08323513a7e432f311bbe05ecb07e3d1 https://doi.org/10.1016/s0022-328x(00)91783-2 Zobrazit plný text záznamu