Homogenization of inorganic material-supported palladium catalysts in Suzuki coupling reaction at room temperature

Autor:	Yueyue Ma, Jinqin Zhou, Xuebing Ma, Qiang Wang
Rok vydání:	2012
Předmět:	Biphenyl compound chemistry.chemical_compound Zirconium Suzuki reaction Chemistry Inorganic chemistry chemistry.chemical_element Porosity Benzene Phosphonate Catalysis Palladium
Zdroj:	Catalysis Science & Technology. 2:1879
ISSN:	2044-4761 2044-4753
Popis:	Novel and homogeneous zirconium phosphonate-supported Pd catalysts with modest BET surface areas (25.6 and 24.7 m2 g−1), high pore volumes (0.39 and 0.73 cc g−1) and nano-sized pores (1–10 nm) were prepared by embedding Na2PdCl4 particles in an organosoluble, porous and layered zirconium phosphonate with a filiform architecture structure for the first time. In the homogeneous palladium-catalyzed Suzuki coupling reaction at room temperature, various substituted benzene bromides with phenylboronic acids were smoothly converted into corresponding biphenyl compounds (82–97% yields), even in cases of electron–rich derivatives. These supported homogeneous Pd catalysts could be quantitatively recovered by using a solid/liquid separation technique and be highly active without loss of catalytic activity in three consecutive runs.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::082711a0954d8d6ee7fc156d34225c01 https://doi.org/10.1039/c2cy00001f Zobrazit plný text záznamu