Electron spin resonance of Mn2+ ions in matrices of polycrystalline samples of Zn4O[(CH3)2CHCOO]6 and Zn4O[(CH3)3CCOO]3

Autor: A. I. Shames, M. I. Belinskii, Boris Tsukerblat, G. A. Popovich, N. V. Gerbeleu, V.E. Fainzil'berg
Rok vydání: 1986
Předmět:
Zdroj: Theoretical and Experimental Chemistry. 21:547-553
ISSN: 1573-935X
0040-5760
Popis: The ESR spectra of polycrystalline samples of Zn4O[(CH3)2CHCOO]6 and Zn4O[(CH3)3CCOO]6, activated by Mn2+ ions at various concentrations, were investigated. An analytical theory was developed for the contour of the hyperfine components of the permitted and various types of “forbidden“ transitions. On the basis of the obtained magnetic-resonance parameters conclusions were reached about the local symmetry and coordination of the Mn2+ ion in the investigated compounds.
Databáze: OpenAIRE