Facile synthesis of MoS2 quantum dots as fluorescent probes for sensing of hydroquinone and bioimaging
Autor: | Fangting Wang, Daowei Li, Xianfeng Hou, Shengxu Wang, Yizhou Yang, Xudong Yang, Lu Li, Zhihua Guo |
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Rok vydání: | 2019 |
Předmět: |
Detection limit
Bioanalysis Materials science Hydroquinone General Chemical Engineering Sodium molybdate 010401 analytical chemistry technology industry and agriculture General Engineering Quantum yield Nanotechnology 02 engineering and technology equipment and supplies 021001 nanoscience & nanotechnology 01 natural sciences Fluorescence 0104 chemical sciences Analytical Chemistry chemistry.chemical_compound chemistry Quantum dot 0210 nano-technology Molybdenum disulfide |
Zdroj: | Analytical Methods. 11:3307-3313 |
ISSN: | 1759-9679 1759-9660 |
Popis: | Recently, transition metal dichalcogenide quantum dots have attracted widespread attention among researchers as fluorescent materials. In this work, a facile bottom–up route is proposed to synthesize water-soluble molybdenum disulfide quantum dots (MoS2 QDs) by using sodium molybdate and cysteine as precursors. The as-prepared spherical MoS2 QDs with an average size of 3.5 nm exhibit intense PL emission, whose quantum yield (QY) is 6.5% (cal.). In particular, the as-synthesized MoS2 QDs show highly sensitive and selective detection of H2Q. The lowest limit of detection can reach 0.3 μM in water, far lower than the estimated wastewater discharge limit of the United States Environmental Protection Agency (EPA) (0.5 mg L−1). What is more, the as-prepared MoS2 QDs exhibited applicability in cell imaging with lower cytotoxicity. Therefore, the as-prepared MoS2 QDs show potential applications in environmental monitoring, bioanalysis, disease diagnosis and treatment, etc. |
Databáze: | OpenAIRE |
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