N-2-(2-Bromo-4,5-dimethoxyphenyl)-1-(2,3,4-trimethoxyphenyl)ethylformamide

Autor:	M. J. Villa, Jost H. Bieri, M. Vlassi, Esther Domínguez, Roland Prewo, Gabriel Germain, Esther Lete, Juan M. Arrieta
Rok vydání:	1991
Předmět:	Steric effects chemistry.chemical_compound Delocalized electron chemistry Stereochemistry Aryl Molecule Ether General Medicine Crystal structure Staggered conformation General Biochemistry Genetics and Molecular Biology Monoclinic crystal system
Zdroj:	Acta Crystallographica Section C Crystal Structure Communications. 47:2115-2118
ISSN:	0108-2701
Popis:	C20H24BrNO6, M(r) = 454.3, monoclinic, Cc, a = 27.479 (4), b = 5.128 (1), c = 21.811 (3) angstrom, beta = 139.35 (1)-degrees, V = 2002 (1) angstrom 3, Z = 4, D(x) = 1.51 Mg m-3, Mo K-alpha radiation, lambda = 0.71069 angstrom, mu = 2.07 mm-1, F(000) = 936, T = 130 K, R = 0.030 for 4151 observed reflections. The X-ray study confirms that in the solid state the structure of the title compound is similar to that inferred from chemical and spectroscopic evidence. Steric hindrance from different chemical groups is minimized by the adoption of a staggered conformation at the central C(8)-C(9) bond, with aryl groups in an anti disposition. There is a delocalized orbital along the N-C-O fragment of the N-formylamino group.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::07fa5fce4da206aa6fce0465f54786bb https://doi.org/10.1107/s0108270191003141 Zobrazit plný text záznamu Plný text