Carboxylate-Bridged Dinuclear Dy2 Single-Molecule Magnets: Synthesis, Structure, and Magnetic Studies

Autor:	Feng Luo, Gong-Ming Sun, Yu-mei Song, Xiao-zhao Tian, Yan Zhu
Rok vydání:	2013
Předmět:	Crystallography chemistry.chemical_compound Ferromagnetism Biocatalysis Chemistry Intramolecular force Supramolecular chemistry Physical chemistry Molecule General Chemistry Crystal structure Carboxylate Coordination geometry
Zdroj:	Australian Journal of Chemistry. 66:98
ISSN:	0004-9425
DOI:	10.1071/ch12377
Popis:	In this work, the synthesis, structure, and magnetic studies of three dinuclear Dy2 compounds, namely Dy2(bpy)2(L)6 (1), Dy2(phen)2(L)6 (2), Dy2(μ-H2O)2(bpy)2(L)6 (3) are reported in detail, where HL, phen, and bpy are 4-chlorobenzoic acid, 1,10-phenanthroline, and 2,2′-bipyridine. Magnetic studies reveal the intramolecular ferromagnetic interaction and single-molecule magnetic properties of these compounds. The fine-tuned single-molecule magnet properties of compounds 1–3, mainly due to the difference of the coordination geometry of DyIII ions, are highlighted.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::07f56b868fee006b7e3b811f4a589e51 https://doi.org/10.1071/ch12377 Zobrazit plný text záznamu Plný text ve formátu HTML
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