Ru-Catalyzed ortho-Selective Diborylation of 2-Arylpyridines toward the Construction of π-Conjugated Functions

Autor:	Jiali Wang, Dongdong Cao, Lili He, Jianguo Yang, Yao Wubing
Rok vydání:	2020
Předmět:	chemistry Organic Chemistry High activity chemistry.chemical_element Conjugated system Boron Selectivity Combinatorial chemistry Ruthenium Catalysis
Zdroj:	The Journal of Organic Chemistry. 85:10245-10252
ISSN:	1520-6904 0022-3263
DOI:	10.1021/acs.joc.0c01211
Popis:	A ruthenium catalytic ortho-C-H diborylation of 2-arylpyridine derivatives, including challenging 2-phenoxypyridine functions, using a remarkably low catalyst loading and a low-cost and bench-stable boron source, has been developed. The novel strategy shows high activity with excellent selectivity and may offer a versatile and green alternative to currently employed high loadings of noble metals or extra additives for the selective borylations.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::07ec34b7dd966727361a139f4f79bc8e https://doi.org/10.1021/acs.joc.0c01211 Zobrazit plný text záznamu